We have investigated the electron pair emission due to single-photon absorption from Ag(100) and Pd(100) surfaces. We are interested in the energy spectra of pairs in particular near the energy cutoff. The sum energy spectra of Ag display a distinctive photon energy dependence. We also observe some fine structure. Near the high-energy cutoff the coincidence rate is too low to determine the energy position of the cutoff. Nevertheless we observe a finite signal if two 5sp electrons near the Fermi level are emitted. For Pd(100) we find sum energy spectra without fine structure and the cutoff region is approached linearly. Within the experimental accuracy the minimum energy to liberate two electrons is twice the work function.