Garcia-Domene, B., Ortiz, H. M., Gomis, O., Sans, J. A., Manjon, F. J., Munoz, A., Rodriguez-Hernandez, P., Achary, S. N., Errandonea, D., Martinez-Garcia, D., Romero Castro, A. H., Singhal, A., Tyagi, A. K.
High-pressure lattice dynamical study of bulk and nanocrystalline In2O3
Journal of Applied Physics 112, (12),pp 123511/1-7 (2012)
The effect of pressure on the vibrational properties of bulk and nanocrystalline powders of cubic
bixbyite-type In2O3 has been investigated at room temperature by means of Raman spectroscopy
up to 31.6 and 30 GPa, respectively. We have been able to follow the pressure dependence of up to
sixteen and seven Raman modes in bulk and nanocrystalline cubic In2O3, respectively. The
experimental frequencies and pressure coefficients of the Raman-active modes of bulk cubic In2O3
at ambient pressure are in good agreement with those predicted by our theoretical ab initio
calculations. Furthermore, a comparison of our experimental data with our calculations for the
Raman modes in rhombohedral corundum and orthorhombic Rh2O3-II structures and with already
reported Raman modes of rhombohedral corundum-type In2O3 at room pressure indicate that
Raman scattering measurements provide no experimental evidence of the cubic to rhombohedral
or cubic to orthorhombic phase transitions either in bulk material or in nanocrystals up to 30 GPa.
TH-2012-64