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Salvietti, M., Ferro, P., Moroni, R., Canepa, M., Mattera, L.

Surface magnetism of an ultrathin Fe/Ag(100) film: influence of O2 and CO adsorption
Surface Science 377-379, pp 481-486 (1997)
The influence of adsorption of O2 and CO on the surface magnetism of a 10 ML film of Fe grown at 120 K on Ag(100) has been investigated by spin polarized metastable deexcitation spectroscopy. The extreme surface sensitivity of this spectroscopy allows us to study the effects of adsorption from exposures as low as ≈ 0.1 L. Oxygen adsorbs dissociatively at 120 K and the O2p states are spin polarized. At this low temperature, oxidation starts from exposures of the order of 1 L and above 3-4 L a non-magnetic oxide layer is formed. CO adsorbs molecularly at T=120 K and then dissociates above room temperature. Following dissociation, carbon atoms do not have any effect on the spin polarization of oxygen and iron states at the surface.

ki-1997-s08